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You've gotten some good advice here already.
You could keep a mini-reef in this system if you do it right. 'Right' is the trick part of it though, and often it falls to experience. These tank are generally dubbed Pico Tanks, though I think 5g falls under the Nano catagory. Experienced care is generally recommended for these setups.
As CrypticAnimal points out when the water evaporates out of the tank it is going to raise the salinity of the water - salt does not evaporate. Most reef organisms are highly sensitive to changes in salinity and would quickly perish under the constant shift.
Heating also becomes a challenge in small tanks. When the lights go out the ambient room temperature will quickly chill the tank. Again, most reef inhabitants do not fare too well to rapid changes in temperature.
You could try setting up a 10 Gallon refugium and plumbing the 5g to that. It would be a challenge, but it would work very well I think.
Don't keep 2 clowns in it. 1 may do fine, though I think he would do much better in a 10g or larger, but two is pushing the limits of water quality if nothing else. A 5g would get dirty quick.
If you are going to do a mini-reef then keep it small: no fish, only a few small corals (mushrooms, polyp colonies, etc), and no anemones or clams.
Some people keep Mantis Shrimp in small tanks. These are predatory reef shrimps and are not welcome in any hobbiest's reef tanks. They are considered pests, but they are remarkably interesting and beautiful creatures. They are very smart and will identify individual people and interact differently with different people.
They eat hermit crabs and snails and you will have to supply them if you want to keep one of these guys. Be careful though, they are dangerous. They can take off a finger if you aren't careful, and they have been known to break the walls of glass and acrylic tanks. I know of a few people that keep them as pets though and they love them.
HTH,
Aaron
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"The only thing that happens fast in saltwater tanks is failure."
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