Hey Dmaaaaax...Welcome to the forum.
I agree with you the KH/GH chart for CO2 only works in theory as there can be lots of buffers other than Carbonates.
The best way available to the hobby to monitor CO2 is a "drop checker". The first time I used one I was astonished at how much more CO2 I needed to reach a level I wanted to work with. I was also surprised to see that it did not gas-off as quickly as I thought during lights off and no injection.
Aside from the normal daytime/night time fluctuations in pH my planted tanks fluctuate a full point 7.2 - 6.2 and back. I start CO2 injection an hour before lights on and stop 1 hour before lights off.