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Since the beneficial bacteria which cycle the aquarium are not free floating, the 5 gallons of old water did not do much for you. The five gallons of water did however probably contain a lot of organic matter which is now breaking down and producing an odor.
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It was 1/2 gallon, now that I've done 2 80% water changes, it's virtually gone. I replace the ammo carb in the external filter. The filter has 3 chambers, bottom has course filter and round ball for bacteria. I fill the middle chamber with ammo carb, top chamber is round balls and fiilter floss. Flow is from bottom to top.
The Amquel and Novaqau also get rid of the chlorine and chlorimenes in the water.
Smell is gone for now. I got some ammonia test strips, and it's less than .25 ppm, hard to read the strips, as there's darkness and color involved. Color is closer to 0 ppm, but darkness is almost .25 ppm. Need to get a better testing kit for later. Hopefully the fresh ammo-carb will help out. May switch to 2 chambers of ammo carb in the external filter.