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the higher acidity of the lower ph made his fins "burn off".
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While I am not trying to pick on you cichlidgirl, but I have never heard of ph differences having the ability to 'burn' off fins and would add that I am in a very similar situation in that I have brought a lot of fish home from an LFS which had a much higher pH than my tank and never had a problem.
However, I would not be surprised if what really happened to your fish is that it came in contact with the bacteria which can cause tail/fin rot, but was healthy enough for its immune system to fight it off...right up until the time in which it experienced a lot of stress from the events related to being bought, transported, and then acclimated to a different aquarium. Or, perhaps your fish was injured at some point which provided the ability for bacteria to infect the fish.
On the same note, it is my understanding that tannins are not a huge concern other then when they are present in vast amounts and the obvious aesthetic related issues...and again, unless the tannis are somehow causing rapid water chemistry changes which may stress fish, the lower pH is also not critical as it relates solely to tail/fin rot...or at least that is my understanding anyways.
In fact, while I don't want to get too far off topic here, to support my comments, check out the pH chart which is located
HERE in order to see that even though we speak of water as being either acidic or alkaline, the pH of water has to be extremely low in order to be acidic enough to have much of a chance to eat away at, or dissolve a fish's fins. In fact, I think you might be surprised to see that pure rain water has a pH (about 5.5) which most of us would be hard pressed to recreate in our tanks to some extent (even if using pure water like distilled or RO, RO/DI). Obviously this suggests that if the lower pH in your tank has the ability to dissolve fins, then we would be in some serious trouble if we ever found ourselves stuck outside in a rainstorm for a long period of time...which isn't the case (although I do realize that pollution and what not may play a role in making that statement false)